Publication |
Sentence |
Publish Date |
Extraction Date |
Species |
Yin-Feng Wang, Ming-Yu Qi, Marco Conte, Zi-Rong Tang, Yi-Jun X. Bimetallic Single Atom/Nanoparticle Ensemble for Efficient Photochemical Cascade Synthesis of Ethylene from Methane. Angewandte Chemie (International ed. in English). 2024-06-11. PMID:38860734. |
herein, we demonstrate a bimetallic design of ag nanoparticles (nps) and pd single atoms (sas) on zno for the cascade conversion of ch4 into c2h4 with the highest production rate compared with previous works. |
2024-06-11 |
2024-06-14 |
Not clear |
Yin-Feng Wang, Ming-Yu Qi, Marco Conte, Zi-Rong Tang, Yi-Jun X. Bimetallic Single Atom/Nanoparticle Ensemble for Efficient Photochemical Cascade Synthesis of Ethylene from Methane. Angewandte Chemie (International ed. in English). 2024-06-11. PMID:38860734. |
mechanistic studies reveal that the synergistic effect of ag nps and pd sas, upon effecting key bond-breaking and -forming events, lowers the overall energy barrier of the activation process of both ch4 and the resulting c2h6, constituting a truly synergistic catalytic system to facilitate the c2h4 generation. |
2024-06-11 |
2024-06-14 |
Not clear |
Peng Zhao, Hao Jiang, Shaowei Yang, Haidong Shen, Runze Gao, Ying Guo, Qiuyu Zhang, Hepeng Zhan. Construction of Low-coordination Cu-C2 Single-Atoms Electrocatalyst Facilitate the efficient electrochemical CO2 Reduction to Methane. Angewandte Chemie (International ed. in English). 2023-10-24. PMID:37875780. |
comprehensive experiments and calculations verified the low-coordination cu-c2 structure not only endowed cu sas center more positive electricity but also promoted the formation of h•, which contributed to the outstanding e-co2rr to ch4 electrocatalytic performance of cu-sas/hgdy. |
2023-10-24 |
2023-11-08 |
Not clear |
Peng Zhao, Hao Jiang, Shaowei Yang, Haidong Shen, Runze Gao, Ying Guo, Qiuyu Zhang, Hepeng Zhan. Construction of Low-coordination Cu-C2 Single-Atoms Electrocatalyst Facilitate the efficient electrochemical CO2 Reduction to Methane. Angewandte Chemie (International ed. in English). 2023-10-24. PMID:37875780. |
constructing cu single-atoms (sas) catalysts is considered as one of the most effective strategies to enhance the performance of electrochemical reduction of co2 (e-co2rr) towards ch4, yet challenging in activity, selectivity, and cumbersome fabrication process. |
2023-10-24 |
2023-11-08 |
Not clear |
Peng Zhao, Hao Jiang, Shaowei Yang, Haidong Shen, Runze Gao, Ying Guo, Qiuyu Zhang, Hepeng Zhan. Construction of Low-coordination Cu-C2 Single-Atoms Electrocatalyst Facilitate the efficient electrochemical CO2 Reduction to Methane. Angewandte Chemie (International ed. in English). 2023-10-24. PMID:37875780. |
notably, this represents the first achievement of preparing cu sas catalysts with cu-c2 coordination structure, which exhibited high co2-to-ch4 selectivity (72.1%) with a high ch4 partial current density of 230.7 ma cm-2, and a turnover frequency reached as high as 2756 h-1, dramatically outperforming currently reported catalysts. |
2023-10-24 |
2023-11-08 |
Not clear |
Peng Zhao, Hao Jiang, Shaowei Yang, Haidong Shen, Runze Gao, Ying Guo, Qiuyu Zhang, Hepeng Zhan. Construction of Low-coordination Cu-C2 Single-Atoms Electrocatalyst Facilitate the efficient electrochemical CO2 Reduction to Methane. Angewandte Chemie (International ed. in English). 2023-10-24. PMID:37875780. |
our work provides a novel h•-transferring mechanism for e-co2rr to ch4 and offers a protocol for the preparation of two-coordinated cu sas catalysts. |
2023-10-24 |
2023-11-08 |
Not clear |
Shenghua Chen, Wen-Hao Li, Wenjun Jiang, Jiarui Yang, Jiexin Zhu, Liqiang Wang, Honghui Ou, Zechao Zhuang, Mingzhao Chen, Xiaohui Sun, Dingsheng Wang, Yadong L. MOF Encapsulating N-Heterocyclic Carbene-Ligated Copper Single-Atom Site Catalyst towards Efficient Methane Electrosynthesis. Angewandte Chemie (International ed. in English). 2021-11-12. PMID:34767294. |
here, n-heterocyclic carbene (nhc)-ligated copper single atom site (cu sas) embedded in metal organic framework is reported (2bn-cu@uio-67), which can achieve an outstanding faradaic efficiency (fe) of 81% for the co2 reduction to ch4 at -1.5 v vs rhe with a current density of 420 ma cm-2. |
2021-11-12 |
2023-08-13 |
Not clear |
Shenghua Chen, Wen-Hao Li, Wenjun Jiang, Jiarui Yang, Jiexin Zhu, Liqiang Wang, Honghui Ou, Zechao Zhuang, Mingzhao Chen, Xiaohui Sun, Dingsheng Wang, Yadong L. MOF Encapsulating N-Heterocyclic Carbene-Ligated Copper Single-Atom Site Catalyst towards Efficient Methane Electrosynthesis. Angewandte Chemie (International ed. in English). 2021-11-12. PMID:34767294. |
this nhc-ligated cu sas catalyst design has great advantages in ch4 electrosynthesis and provides ideas for the commercial production of ch4. |
2021-11-12 |
2023-08-13 |
Not clear |
Diwakar Vyas, Aklilu W Alemu, Sean M McGinn, Stephane M Duval, Maik Kindermann, Karen A Beauchemi. The combined effects of supplementing monensin and 3-nitrooxypropanol on methane emissions, growth rate, and feed conversion efficiency in beef cattle fed high-forage and high-grain diets. Journal of animal science. vol 96. issue 7. 2018-10-23. PMID:29741701. |
data were analyzed using a mixed procedure of sas with pen as experimental unit (except ch4). |
2018-10-23 |
2023-08-13 |
cattle |